SCIENTIFIC FOUNDATIONS FOR THE CREATION OF HIGHLY ENTROPIC CARBIDE AND OXIDE NANOCOATINGS ON SUPERHARD MATERIAL CORTINITE
Abstract
The possibility of creating highly entropic carbide and oxide nanocoatings on superhard material Cortinitis based on hafnium, zircon, molybdenum, tungsten, yttrium and nickel was investigated. An investigation was made of the production of nitride, carbide, boride and oxide coatings and nitrides, carbides, borides and oxides directly in the body of the material at ion energies in the range from 200 to 2·104 eV with charge numbers from 1 to 3. Important characteristics were obtained: the grain volume for all the ions and nitrogen, carbon, boron and oxygen ions listed and their depth, which allows us to evaluate the layers of nanostructures or submicrostructures that can be formed by these high-entropy coatings. Moreover, it is shown that it is possible to avoid the production of intermetallic compounds due to the high mobility of nitrogen ions.
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Yeh, J. W., Chen, Y. L., Lin, S. J. , Chen, S. K. High-Entropy Alloys – A New Era of Exploitation. Materials Science Forum. 2007, vol. 560, pp. 1–9.
Ivchenko, M. V., Pushin, V. G, Wanderka, N. Visokoentropіjnі ekvіatomnі splavi AlCrFeCoNiCu: gіpotezi i eksperimental'nі fakti [Highly entropic equiatomic alloys AlCrFeCoNiCu: a hypothesis and experimental facts]. Zhurnal tehnіchnoї fіziki - Journal of Technical Physics, 2014, vol. 84, no. 2, pp. 57–64.
Blinkov, I. V., Volhonskij, A. O., Anikin, V. N., Petrzhik, M. I., Derevcova, D. E. Fazovyj sostav i svojstva iznosostoj-kih Ti-Al-Cr-Zr-Nb-N pokrytij, poluchennyh meto-dom fizicheskogo osazhdenija iz gazovoj fazy [Phase composition and properties of wear-resistant coatings Ti-Al-Cr-Zr-Nb-N obtained by the method of physical deposition from the gas phase]. Fizika i himija obrabotki materialov - Physics and chemistry of material processing, 2010, vol. 37, pp. 37–44.
Pogrebnjak, A. D., Bagdasarjan, A. A., Jakushhenko, I. V., Beresnev, V. M. Struktura i svojstva vysokojentropijnih splavov i nitridnih pokrytij na ih osnov [Structure and properties of high-entropic alloys and nitride coatings based on them]. Uspehi himii - Success of chemistry, 2014, no. 83 (11), pp. 1027–1061.
Kostjuk, G. I. Jeffektivnyj rezhushhij instrument s nanopokrytijami i nanostrukturnymi modificirovannymi slojami: monografija-spravochnik [Effective cutting tools with nanocoatings and nanostructured modified layers]. Kharkov, «Planeta-Print» Publ., 2016, book 1. 735 p.
Kostjuk, G. I. Jeffektivnye pokrytija i modificirovannye uprochnennye sloi na rezhushhih instrumentah [Effective coatings and modified reinforced layers on cutting tools ]. Кiev, izd. centr Mezhdunar. akademii nauk i innovac. tehnologij Publ., 2012. 728 p.
Kostjuk, G. I. Nanotehnologii: vybor tehno-logicheskih parametrov i ustanovok, proizvoditel'nost' obrabotki, fiziko-mehanicheskie ha-rakteristiki nanostruktur [Nanotechnologies: selection of process parameters and plants, manufacturing efficiency, physical and mechanical properties of nanostructures]. Кiev, izd. centr Mezhdunar. akademii nauk i innovac. tehnologij Publ., 2014. 472 p.
Kostjuk, G. I. Nanotehnologii: teorija, jekspe-riment, tehnika, perspektivy [Nanotechnologies: theory, experiment, technology, prospects]. Кiev, izd. centr Mezhdunar. akademii nauk i innovac. tehnologij Publ., 2012. 648 p.
Kostjuk, G. I. Nanostruktury i nanopokrytija: perspektivy i real'nost' [Nanostructures and nano-coating: prospects and reality]. Kharkov, Nats. Aerokosm. un-t «Khar'k. aviats. in-t» Publ., 2009. 406 p.
Kostjuk, G. I. Jeffektivnyj rezhushhij instrument s pokrytiem i uprochnennym sloem [Efficient cutting tool with a coating and a reinforced layer]. Kharkov, Nats. Aerokosm. un-t «Khar'k. aviats. in-t» Publ., 2007. 633 p.
Kostjuk, G. I. Fiziko-tehnicheskie osnovy nanesenija pokrytij, ionnoj implantacii i ionnogo legirovani, lazernoj obrabotki i uprochnenija, kombinirovannyh tehnologij [Physical and technical basis of coating, ion implantation and ion doping, laser processing and hardening, combined technologies]. Кiev, AINU Publ., 2002, book 2. 1030 p.
DOI: https://doi.org/10.32620/aktt.2017.3.05